Specialty Gases

Specialty Gases

Tetrafluoromethane

Tetrafluoromethane (CF₄)

High-Performance Etching Gas for Advanced Manufacturing

Tetrafluoromethane (CF₄), a colorless, non-flammable gas with exceptional thermal stability, serves as a critical halocarbon in precision industries. With a boiling point of -128°C and low global warming potential (GWP 7,390), it combines chemical inertness with high plasma selectivity, making it ideal for mission-critical processes. Tetrafluoromethane is used in electrical insulation, aluminum production, semiconductor etching, trace gas detection, and cosmic ray detection. Our CF₄ is supplied in ISO-certified cylinders at ≥99.999% purity (Grade 5.0).

Specifications

YIGAS is a tetrafluoromethane gas supplier providing 99.999% electronic-grade CF₄ for semiconductor plasma etching, electronics manufacturing and selected chamber-cleaning processes.

Our CF₄ gas is supplied in 47L cylinders with a CGA580 valve and approximately 30 kg net filling weight. Defined limits for moisture, HF, oxygen, nitrogen, hydrocarbons and other fluorinated impurities help customers evaluate the complete gas specification rather than relying only on the 5N purity level.

YIGAS supports semiconductor manufacturers, electronic material suppliers and specialty gas distributors with specification review, qualification orders, multi-cylinder supply and scheduled commercial deliveries.

Need 99.999% CF₄ for semiconductor production? Send us your specification, cylinder quantity and destination for a quotation.

CAS No. 75-73-0
UN No. 1982
EINECS No. 200-896-5
Molecular Weight 88
Appearance Colorless, odorless
Melting Point -184 °C
Boiling Point -128.1 °C
Density 3.72 kg/m³
DOT Class 2.2
Label Non-flammable Gas



Electronic Grade Tetrafluoromethane 
Specification99.999%
O2+Ar≤ 1 ppm
N2≤ 2 ppm
H2≤ 0.3 ppm
CO≤ 0.3 ppm
CO2≤ 0.3 ppm
SF6≤ 0.3 ppm
THC≤ 0.3 ppm
CHF3≤ 0.3 ppm
OFC≤ 1 ppm
H2O≤ 1 ppm
HF≤ 0.1 ppm


Packaging Specifications

Gas Container >>
Cylinder SpecificationsContent
Cylinder CapacityValveGas Net Weight
47LCGA58030 kg


CF₄ Gas for Semiconductor Plasma Etching

The primary commercial application of electronic-grade tetrafluoromethane is semiconductor plasma etching.

When CF₄ is activated in plasma, fluorine-containing reactive species are generated and can be used to etch selected silicon-containing materials.

Typical applications include:

  • Silicon etching

  • Silicon dioxide etching

  • Silicon nitride processing

  • Dielectric material etching

  • Wafer fabrication

  • Plasma surface processing

  • Semiconductor process development

  • Selected chamber-cleaning processes

CF₄ may be used alone or together with other gases depending on the required etch rate, profile and selectivity.

For semiconductor manufacturers, the key purchasing factors are:

  • CF₄ purity

  • Moisture and HF levels

  • Oxygen and nitrogen content

  • Other fluorocarbon impurities

  • Batch consistency

  • Cylinder cleanliness

  • Valve compatibility

  • Supply continuity

YIGAS's broader semiconductor electronics gas solutions also include nitrogen, argon, ammonia and nitrogen trifluoride for different stages of electronic manufacturing.

Why CF₄ Purity Matters in Semiconductor Processes

For semiconductor buyers, 99.999% purity alone is not enough to qualify a CF₄ supplier.

Two products labeled 5N CF₄ may have different impurity profiles.

Moisture

Moisture can affect gas system cleanliness and process stability. YIGAS limits H₂O to ≤1 ppm in the published electronic-grade specification.

Hydrogen Fluoride

HF is a corrosive fluorine-containing impurity. The standard YIGAS specification limits HF to ≤0.1 ppm.

Oxygen and Nitrogen

Oxygen, argon and nitrogen may enter through raw materials, filling equipment or cylinder preparation. Their levels should remain consistent between production batches.

Other Fluorocarbons

CHF₃, SF₆ and other fluorinated compounds may affect plasma chemistry in sensitive processes.

This is why semiconductor procurement teams should review both the total purity and the complete COA.

For a deeper supplier qualification checklist, see our guide on how to select a high-purity CF₄ gas supplier for semiconductor manufacturing.


CF₄ Cylinder and Packaging

YIGAS provides electronic-grade CF₄ in a standard commercial cylinder configuration.

Packaging ItemSpecification
Cylinder Capacity47L
Valve ConnectionCGA580
CF₄ Net WeightApproximately 30 kg
Product FormCompressed / liquefied gas in cylinder
Standard SupplyIndividual or multi-cylinder shipment

Before ordering, customers should confirm:

  • Cylinder capacity

  • Required valve connection

  • Gas cabinet compatibility

  • Regulator connection

  • Quantity per shipment

  • Customer labeling

  • Cylinder return arrangement

  • Destination-country cylinder standard

Customers requiring alternative packaging or labeling can submit their requirements through our custom gas supply services.


CF₄ Supply for Semiconductor Manufacturers

Semiconductor fabs generally require more than a one-time cylinder purchase.

After a gas is qualified for a production process, buyers need consistent specifications and reliable repeat deliveries.

YIGAS can support:

Qualification Orders

Customers can review the product specification, packaging and available quality documents before introducing the gas into the qualification process.

Commercial Multi-Cylinder Supply

Once the product is approved, multiple cylinders can be coordinated according to production demand.

Scheduled Deliveries

For recurring CF₄ consumption, monthly or quarterly shipment schedules can be discussed.

Annual Supply Planning

Customers with predictable demand can provide an annual forecast to help coordinate cylinder availability, filling and international logistics.

Distributor Supply

Electronic specialty gas distributors can discuss recurring purchases, destination-specific packaging and long-term supply arrangements.

For commercial inquiries, providing monthly and annual consumption is more useful than requesting only a one-cylinder price.

CF₄ for Chamber Cleaning

CF₄ can also be used in selected plasma chamber-cleaning applications.

Reactive fluorine species produced in plasma can remove certain silicon-containing residues from process equipment.

However, CF₄ and nitrogen trifluoride are not interchangeable in every cleaning process.

The appropriate gas depends on:

  • Process equipment

  • Chamber design

  • Residue composition

  • Plasma source

  • Cleaning recipe

  • Gas utilization

  • Exhaust and abatement system

For customers deciding between these two gases, our technical article on NF₃ gas vs CF₄ gas for semiconductor chamber cleaning provides a more detailed comparison.

The product page should remain focused on CF₄ specifications and supply rather than reproducing the full process comparison here.

CF₄ vs Other Semiconductor Etching Gases

CF₄ is one of several fluorocarbon gases used in plasma processing.

Other gases may provide different levels of fluorine activity, polymer formation and profile control.

For example, C₄F₈ is often considered where stronger sidewall passivation or different etch-profile control is required.

The correct gas cannot be selected only by cylinder price.

Process engineers normally consider:

  • Material being etched

  • Etch rate

  • Selectivity

  • Profile control

  • Mask compatibility

  • Plasma conditions

  • Chamber cleaning requirements

Customers comparing fluorocarbon gases can read our detailed guide on CF₄ vs C₄F₈ for plasma etching.

SEMI C3.40 and Customer Specifications

SEMI C3.40 provides a specification for carbon tetrafluoride used in semiconductor manufacturing.

The SEMI standard covers 99.997% quality CF₄.

YIGAS currently publishes a higher nominal purity of 99.999%, but a higher total purity does not automatically confirm compliance with every parameter or test method required by SEMI C3.40.

If your purchasing specification requires:

  • SEMI C3.40

  • Customer-specific impurity limits

  • Specific analytical methods

  • Specific reporting limits

  • Additional contaminants

  • Batch-specific documentation

please submit the complete requirement before order confirmation.

YIGAS will compare the requested specification with the available product and confirm what can be supplied.

Quality Control for Electronic-Grade CF₄

Stable CF₄ quality depends on more than purification.

Cylinder preparation, filling, testing and transportation all influence the gas received at the customer site.

YIGAS focuses on:

  • Raw gas quality control

  • Purification

  • Cylinder preparation

  • Moisture control

  • Controlled filling

  • Impurity testing

  • Cylinder identification

  • Batch traceability

  • Shipment records

  • Quality follow-up

Available customer documents may include:

  • Product specification

  • Safety Data Sheet

  • Certificate of Analysis

  • Cylinder specification

  • Valve information

  • Batch identification

  • Export documentation

Customers requiring a batch-specific COA or additional test parameters should include these requirements in the RFQ.

Batch Consistency for Qualified Semiconductor Processes

Once a CF₄ source has been qualified, unexpected changes can create additional testing or requalification work.

Commercial semiconductor buyers should therefore pay attention to:

  • Stable impurity limits

  • Consistent cylinder preparation

  • Stable valve configuration

  • Product batch identification

  • Filling location

  • Analytical consistency

  • Product change notification

  • Supply continuity

YIGAS can review recurring quality and documentation requirements before long-term supply begins.

Our article on CF₄ gas supply instability and cylinder contamination risks discusses these issues in greater technical detail.

Supply Support for High-Volume CF₄ Buyers

YIGAS supports semiconductor manufacturers and specialty gas distributors with recurring CF₄ requirements.

Purchasing RequirementSupply Support
Product QualificationSpecification and packaging review
Trial SupplyQualification cylinder requirements
Commercial SupplyMulti-cylinder shipments
Regular ConsumptionMonthly or quarterly scheduling
Annual DemandForecast-based supply planning
Distributor OrdersCommercial volume and packaging review
Custom SpecificationImpurity requirement evaluation
International OrdersDangerous-goods logistics coordination

For large-volume buyers, please provide:

  • Cylinders required per shipment

  • Monthly CF₄ consumption

  • Estimated annual demand

  • Required delivery frequency

  • Destination country

  • Required safety stock

  • Empty-cylinder return requirements

This helps us evaluate a realistic supply plan rather than quoting an isolated cylinder.


International CF₄ Supply

Electronic specialty gas customers often require international shipment from the production site to semiconductor fabs or regional gas distribution centers.

YIGAS can evaluate:

  • Destination country

  • Destination port

  • Cylinder certification

  • Dangerous-goods documentation

  • Customer labeling

  • Export packaging

  • Shipping schedule

  • Cylinder return requirements

International availability depends on the destination, carrier acceptance and applicable regulations.

Providing the destination information at the RFQ stage allows transportation requirements to be reviewed before the order is confirmed.


Safety and Environmental Considerations

CF₄ is nonflammable and chemically stable under normal conditions, but it can displace oxygen in enclosed spaces.

Gas cylinders should be stored in a ventilated area and used with compatible regulators, valves and gas delivery systems.

During plasma processing, fluorine-containing decomposition products may be generated. Semiconductor facilities should therefore use appropriate exhaust and abatement systems based on their process conditions.

CF₄ is also a long-lived fluorinated greenhouse gas. Users should control leaks, optimize process consumption and manage exhaust emissions according to applicable regulations and facility environmental programs.

This core product page does not need to carry a long environmental discussion. Detailed process and environmental assessments should be handled by the customer's engineering and EHS teams.


Why Choose YIGAS as Your CF₄ Gas Supplier?

99.999% Electronic-Grade CF₄

YIGAS supplies 5N tetrafluoromethane designed for semiconductor and electronic manufacturing applications.

Defined Impurity Specification

Published limits cover O₂ + Ar, N₂, H₂, CO, CO₂, SF₆, hydrocarbons, CHF₃, other fluorocarbons, moisture and HF.

Commercial Cylinder Supply

The standard configuration is a 47L cylinder with a CGA580 valve and approximately 30 kg CF₄ net content.

Semiconductor Gas Portfolio

In addition to CF₄, YIGAS supplies electronic specialty gases including ammonia and NF₃, as well as nitrogen and argon for semiconductor manufacturing.

Quality and Traceability Support

Product, batch, cylinder and shipment records can be managed according to agreed customer requirements.

Recurring Supply Support

Qualification orders can transition into scheduled multi-cylinder or long-term commercial supply.

International Logistics

YIGAS can coordinate cylinder packaging, dangerous-goods documentation and international shipping requirements.

Technical Specification Review

Customers can submit fab specifications or individual impurity limits before quotation to reduce specification mismatches during qualification.


Request a CF₄ Gas Quotation

Looking for a reliable tetrafluoromethane gas supplier for semiconductor plasma etching or electronic manufacturing?

Send YIGAS:

  • Required CF₄ purity

  • Target impurity limits

  • Process application

  • Cylinder quantity

  • Estimated monthly or annual consumption

  • Valve and packaging requirements

  • Destination country and port

  • Required quality documents

  • Delivery schedule

Our team will review the technical, packaging and commercial requirements and provide a suitable electronic-grade CF₄ supply proposal.

Request 99.999% CF₄ Specification & COA

Get a Multi-Cylinder CF₄ Quotation

Discuss Long-Term Semiconductor Gas Supply


Key Applications

Semiconductor Electronics

The semiconductor and electronics manufacturing industries have extremely high requirements for gas purity and stability. YIGAS provides nitrogen (N₂), argon (Ar), ammonia (NH₃), carbon tetrafluoride (CF₄), and nitrogen trifluoride (NF₃) to meet the needs of applications throughout the entire process from wafer fabrication to display panels. 



Safety & Compliance

NFPA 704 Rating: Health 1 / Flammability 0 / Reactivity 0

Storage: Dedicated ventilated facilities <30°C, segregated from oxidizers.

Emergency protocols: On-site gas detection and neutralization scrubbers.

FAQ

Why Choose YIGAS?

Team

Global Leadership: Management team with multinational and listed company backgrounds, backed by decades of expertise in the industrial gases sector.

End-to-End Expertise: Integrated capabilities spanning production, operation, R&D, commercialization, and quality assurance in gas industry.

Technical Excellence: Advanced knowledge in gas/chemical synthesis, purification, and process optimization, supported by on-demand technical application services.

R & D

Innovation-Driven: Focus on cutting-edge R&D to deliver safer, sustainable, and cost-effective gas solutions.

Full-Cycle Development: From concept design to scalable production, ensuring seamless technology transfer and market readiness.

Service

Customer-Centric Solutions: Tailored services with flexibility, professionalism, and 24/7 dedicated support.

Value Proposition: Guaranteed supply chain stability, safety compliance (ISO/OSHA standards), and total cost optimization.

Quality

Zero-Compromise Standards: Rigorous QC protocols for both in-house and outsourced products, validated by third-party certifications.

Operational Precision: Expertise in lean production management, analytical quality control, and continuous process improvement.

We Look Forward To Working With You.